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Lewis acid-promoted α-hydroxy β-dicarbonyl to α-ketol ester rearrangement
The decarbomethoxylation reaction of a substituted α-hydroxy-α-carbomethoxy pentacyclic substituted ketone, used as an advanced intermediate in the synthesis of the alkaloid aspidophytine, can be elected by heating with MgI(2) in CH(3)CN. The reaction was shown to proceed by a novel α-hydroxy β-dica...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1805679/ https://ncbi.nlm.nih.gov/pubmed/17330147 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2006.09.071 |
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