טוען...
Direct C-C Coupling of Ethylene and α-Olefins with Diols, Ketols or Hydroxy Esters via Osmium(0) Catalyzed Transfer Hydrogenation
Osmium(0) complexes derived from Os(3)(CO)(12) and XPhos (2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) catalyze the C-C coupling of α-hydroxy esters 1a-1i, α-ketols 1j-1o or 1,2-diols dihydro-1j-1o with ethylene 2a to form ethylated tertiary alcohols 3a-3o. As illustrated in couplings of 1...
שמור ב:
| הוצא לאור ב: | J Org Chem |
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| Main Authors: | , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2016
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5096948/ https://ncbi.nlm.nih.gov/pubmed/27580269 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01923 |
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