On the feasibility of N(2) fixation via a single-site Fe(I)/Fe(IV) cycle: Spectroscopic studies of Fe(I)(N(2))Fe(I), Fe(IV) [Image: see text] N, and related species

The electronic properties of an unusually redox-rich iron system, [PhBP(R)(3)]Fe [Image: see text] N(x) (where [PhBP(R)(3)] is [PhB(CH(2)PR(2))(3)](−)), are explored by Mössbauer, EPR, magnetization, and density-functional methods to gain a detailed picture regarding their oxidation states and elect...

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Auteurs principaux: Hendrich, Michael P., Gunderson, William, Behan, Rachel K., Green, Michael T., Mehn, Mark P., Betley, Theodore A., Lu, Connie C., Peters, Jonas C.
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 2006
Sujets:
Nitrogen Fixation Special Feature
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC1693871/
https://ncbi.nlm.nih.gov/pubmed/17090681
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0604402103
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