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A methyldiazene (HN [Image: see text] N [Image: see text] CH(3))-derived species bound to the nitrogenase active-site FeMo cofactor: Implications for mechanism
Methyldiazene (HN [Image: see text] N [Image: see text] CH(3)) isotopomers labeled with (15)N at the terminal or internal nitrogens or with (13)C or (2)H were used as substrates for the nitrogenase α-195(Gln)-substituted MoFe protein. Freeze quenching under turnover traps an S = ½ state that has bee...
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| Autori principali: | , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
National Academy of Sciences
2006
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1693872/ https://ncbi.nlm.nih.gov/pubmed/17088552 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0602130103 |
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