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Stereoselective synthesis of the C(1)–C(13) segment of dolabelide B

The efficient construction of the C(1)–C(13) segment of dolabelide B is described. A key element of the synthesis entails BITIP catalyzed asymmetric methallylation to establish the C(7) stereocenter, which was then used to direct the stereoselective installation of the C(9) and C(11) centers through...

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Detalhes bibliográficos
Main Authors: Keck, Gary E., McLaws, Mark D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC1540402/
https://ncbi.nlm.nih.gov/pubmed/16909163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2005.04.146
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