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Stereoselective synthesis of the C(1)–C(13) segment of dolabelide B

The efficient construction of the C(1)–C(13) segment of dolabelide B is described. A key element of the synthesis entails BITIP catalyzed asymmetric methallylation to establish the C(7) stereocenter, which was then used to direct the stereoselective installation of the C(9) and C(11) centers through...

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Bibliografiske detaljer
Main Authors: Keck, Gary E., McLaws, Mark D.
Format: Artigo
Sprog:Inglês
Udgivet: 2005
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC1540402/
https://ncbi.nlm.nih.gov/pubmed/16909163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2005.04.146
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