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Total Synthesis of Dolabelide C: A Phosphate-Mediated Approach

The first synthesis of dolabelide C (1), a cytotoxic marine macrolide, is reported utilizing a phosphate tether-mediated approach. Bicyclic phosphates (S,S,S(P))-5 and (R,R,R(P))-5 serve as the central building blocks for the construction of two major 1,3-anti-diol subunits in 1 through selective cl...

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Detalhes bibliográficos
Main Authors: Hanson, Paul R., Chegondi, Rambabu, Nguyen, John, Thomas, Christopher D., Waetzig, Joshua D., Whitehead, Alan
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3150593/
https://ncbi.nlm.nih.gov/pubmed/21528846
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo2003506
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