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A Multifaceted Phosphate Tether: Application to the C15-C30 Subunit of Dolabelides A-D

Construction of the C15-C30 subunit of dolabelide utilizing a temporary phosphate tether is described. Two routes are reported that make use of the orthogonal protecting- and leaving-group properties innate to phosphate esters. One route relies on a selective terminal oxidation, while a second utili...

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Autors principals: Whitehead, Alan, Waetzig, Joshua D., Thomas, Christopher D., Hanson, Paul R.
Format: Artigo
Idioma:Inglês
Publicat: 2008
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2641022/
https://ncbi.nlm.nih.gov/pubmed/18324822
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8001865
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