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Stereoselective synthesis of the C(1)–C(13) segment of dolabelide B

The efficient construction of the C(1)–C(13) segment of dolabelide B is described. A key element of the synthesis entails BITIP catalyzed asymmetric methallylation to establish the C(7) stereocenter, which was then used to direct the stereoselective installation of the C(9) and C(11) centers through...

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Autors principals: Keck, Gary E., McLaws, Mark D.
Format: Artigo
Idioma:Inglês
Publicat: 2005
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC1540402/
https://ncbi.nlm.nih.gov/pubmed/16909163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2005.04.146
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