Rhodium (II) Catalyzed Wolff Rearrangement of a Carbenoid Derived from an Indolyl Diazopropanedione
The Rhodium (II) acetate catalyzed reaction of 3-diazo-1-(indol-3-yl)- propane-1,2-dione did not give the expected intramolecularcyclization product, affording only 3-acetylindole in 70% yield.A reaction mechanism which involves a Wolff rearrangement is proposed.
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| 發表在: | Journal of the Mexican Chemical Society |
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| Principais autores: | , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Sociedad Química de México
2004
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| 主題: | |
| 在線閱讀: | https://www.redalyc.org/articulo.oa?id=47548109 |
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