Synthesis and Properties of 2-diazo-1-[2-(thiophen-2-ylmethoxy)- phenyl]-ethanone. Intramolecular Cyclization Through a Carbenoid Intermediate
The synthesis of 2-diazo-1-[2-(thiophen-2-ylmethoxy)-phenyl]-ethanone (1) is described. The procedure involves an aromaticnucleophilic substitution between the sodium 2-thiophenylmethoxide and 2-fluorobenzaldehyde, the subsequent mild-conditionoxidation to the corresponding carboxylic acid, and fina...
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| Publicat a: | Journal of the Mexican Chemical Society |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Sociedad Química de México
2003
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| Matèries: | |
| Accés en línia: | https://www.redalyc.org/articulo.oa?id=47547221 |
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