Rhodium (II) Catalyzed Wolff Rearrangement of a Carbenoid Derived from an Indolyl Diazopropanedione
The Rhodium (II) acetate catalyzed reaction of 3-diazo-1-(indol-3-yl)- propane-1,2-dione did not give the expected intramolecularcyclization product, affording only 3-acetylindole in 70% yield.A reaction mechanism which involves a Wolff rearrangement is proposed.
Shranjeno v:
| izdano v: | Journal of the Mexican Chemical Society |
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| Principais autores: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Sociedad Química de México
2004
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| Teme: | |
| Online dostop: | https://www.redalyc.org/articulo.oa?id=47548109 |
| Oznake: |
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