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Highly Diastereoselective Addition of a Racemic b-Alanine Enolate Derivative to Electrophiles
b-Alanine, an inexpensive b-amino acid, was convertedinto the 2-phenylperhydropyrimidin-4-one derivative (1), which canbe alkylated with high diastereoselectivity via the corresponding enolate.The high stereoselectivity observed for the reaction of (1)-Liwith electrophiles seems to be due to steric...
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| Publicado en: | Journal of the Mexican Chemical Society |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Sociedad Química de México
2001
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| Materias: | |
| Acceso en línea: | https://www.redalyc.org/articulo.oa?id=47545409 |
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