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Iron-Catalyzed Vinylsilane Dimerization and Cross-Cycloadditions with 1,3-Dienes: Probing the Origins of Chemo- and Regioselectivity
The selective, intermolecular, homodimerization and cross-cycloaddition of vinylsilanes with unbiased 1,3-dienes, catalyzed by a pyridine-2,6-diimine (PDI) iron complex is described. In the absence of a diene coupling partner, vinylsilane hydroalkenylation products were obtained chemoselectively wit...
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| Udgivet i: | ACS Catal |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8317497/ https://ncbi.nlm.nih.gov/pubmed/34336370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c04608 |
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