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Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes

A family of single-component iron precatalysts for the [4+4]-cyclodimerization and intermolecular cross-[4+4]-cycloaddition of monosubstituted 1,3-dienes is described. Cyclooctadiene products were obtained with high regioselectivity, and catalyst-controlled access to either cis- or trans-diastereome...

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Publicat a:J Am Chem Soc
Autors principals: Kennedy, C. Rose, Zhong, Hongyu, Macaulay, Rachel L., Chirik, Paul J.
Format: Artigo
Idioma:Inglês
Publicat: 2019
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6541524/
https://ncbi.nlm.nih.gov/pubmed/31060353
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02443
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