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Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts
The selective, intermolecular [1,4]-hydrovinylation of conjugated dienes with unactivated α-olefins catalyzed by α-diimine iron complexes is described. Value-added “skipped” diene products were obtained with exclusive [1,4]-selectivity, and the formation of branched, (Z)-olefin products was observed...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5857361/ https://ncbi.nlm.nih.gov/pubmed/29414238 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b00245 |
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