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Increasing reactivity by incorporating π-acceptor ligands into coordinatively unsaturated thiolate-ligated iron(II) complexes

Reported herein is the structural, spectroscopic, redox, and reactivity properties of a series of iron complexes containing both a π-donating thiolate, and π-accepting N-heterocycles in the coordination sphere, in which we systematically vary the substituents on the N-heterocycle, the size of the N-...

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Vydáno v:Inorganica Chim Acta
Hlavní autoři: Toledo, Santiago, Yan Poon, Penny Chaau, Gleaves, Morgan, Rees, Julian, Rogers, Dylan M., Kaminsky, Werner, Kovacs, Julie A.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2021
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8301228/
https://ncbi.nlm.nih.gov/pubmed/34305163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2021.120422
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