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Isolation of Neutral, Mono‐, and Dicationic B(2)P(2) Rings by Diphosphorus Addition to a Boron−Boron Triple Bond
The NHC‐stabilised diboryne (B(2)(SIDep)(2); SIDep=1,3‐bis(2,6‐diethylphenyl)imidazolin‐2‐ylidene) undergoes a high‐yielding P−P bond activation with tetraethyldiphosphine at room temperature to form a B(2)P(2) heterocycle via a diphosphoryldiborene by 1,2‐diphosphination. The heterocycle can be oxi...
Tallennettuna:
| Julkaisussa: | Angew Chem Int Ed Engl |
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| Päätekijät: | , , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
John Wiley and Sons Inc.
2021
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8252364/ https://ncbi.nlm.nih.gov/pubmed/33844394 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202102218 |
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