Isolation of Neutral, Mono‐, and Dicationic B(2)P(2) Rings by Diphosphorus Addition to a Boron−Boron Triple Bond

The NHC‐stabilised diboryne (B(2)(SIDep)(2); SIDep=1,3‐bis(2,6‐diethylphenyl)imidazolin‐2‐ylidene) undergoes a high‐yielding P−P bond activation with tetraethyldiphosphine at room temperature to form a B(2)P(2) heterocycle via a diphosphoryldiborene by 1,2‐diphosphination. The heterocycle can be oxi...

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Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Brückner, Tobias, Fantuzzi, Felipe, Stennett, Tom E., Krummenacher, Ivo, Dewhurst, Rian D., Engels, Bernd, Braunschweig, Holger
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2021
Teme:
Communications
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252364/
https://ncbi.nlm.nih.gov/pubmed/33844394
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202102218
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