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Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond
An N‐heterocyclic‐carbene‐stabilized diboryne undergoes rapid, high‐yielding and catalyst‐free hydroamination reactions with primary amines, yielding 1‐amino‐2‐hydrodiborenes, which can be considered boron analogues of enamines. The electronics of the organic substituent at nitrogen influence the st...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
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| Hoofdauteurs: | , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2020
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7839459/ https://ncbi.nlm.nih.gov/pubmed/33058434 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012101 |
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