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Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond

An N‐heterocyclic‐carbene‐stabilized diboryne undergoes rapid, high‐yielding and catalyst‐free hydroamination reactions with primary amines, yielding 1‐amino‐2‐hydrodiborenes, which can be considered boron analogues of enamines. The electronics of the organic substituent at nitrogen influence the st...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Brückner, Tobias, Heß, Merlin, Stennett, Tom E., Rempel, Anna, Braunschweig, Holger
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839459/
https://ncbi.nlm.nih.gov/pubmed/33058434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202012101
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