Reduction and Rearrangement of a Boron(I) Carbonyl Complex

The one‐electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)‐stabilized arylborylene carbonyl complex yields a dimeric borylketyl radical anion, resulting from an intramolecular aryl migration to the CO carbon atom. Computational analyses support the existence of a [(CAAC)B(CO)Ar](.−) radical...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Rang, Maximilian, Fantuzzi, Felipe, Arrowsmith, Merle, Krummenacher, Ivo, Beck, Eva, Witte, Robert, Matler, Alexander, Rempel, Anna, Bischof, Tobias, Radacki, Krzysztof, Engels, Bernd, Braunschweig, Holger
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898892/
https://ncbi.nlm.nih.gov/pubmed/33191596
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014167
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