Twisting versus Delocalization in CAAC‐ and NHC‐Stabilized Boron‐Based Biradicals: The Roles of Sterics and Electronics

Twisted boron‐based biradicals featuring unsaturated C(2)R(2) (R=Et, Me) bridges and stabilization by cyclic (alkyl)(amino)carbenes (CAACs) were recently prepared. These species show remarkable geometrical and electronic differences with respect to their unbridged counterparts. Herein, a thorough co...

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Опубликовано в: :Chemistry
Главные авторы: Schmid, Paul, Fantuzzi, Felipe, Klopf, Jonas, Schröder, Niklas B., Dewhurst, Rian D., Braunschweig, Holger, Engel, Volker, Engels, Bernd
Формат: Artigo
Язык:Inglês
Опубликовано: John Wiley and Sons Inc. 2021
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC8048672/
https://ncbi.nlm.nih.gov/pubmed/33225473
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004619
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