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Directed regioselective ortho,ortho′-magnesiations of aromatics and heterocycles using sBu(2)Mg in toluene

Aryl azoles are ubiquitous as bioactive compounds and their regioselective functionalization is of utmost synthetic importance. Here, we report the development of a toluene-soluble dialkylmagnesium base sBu(2)Mg. This new reagent allows mild and regioselective ortho-magnesiations of various N-arylat...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Hess, Andreas, Prohaska, Jan P., Doerrich, Sabrina B., Trauner, Florian, Lutter, Ferdinand H., Lemaire, Sébastien, Wagschal, Simon, Karaghiosoff, Konstantin, Knochel, Paul
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8221067/
https://ncbi.nlm.nih.gov/pubmed/34221323
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01777b
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