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Directed regioselective ortho,ortho′-magnesiations of aromatics and heterocycles using sBu(2)Mg in toluene
Aryl azoles are ubiquitous as bioactive compounds and their regioselective functionalization is of utmost synthetic importance. Here, we report the development of a toluene-soluble dialkylmagnesium base sBu(2)Mg. This new reagent allows mild and regioselective ortho-magnesiations of various N-arylat...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8221067/ https://ncbi.nlm.nih.gov/pubmed/34221323 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01777b |
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