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Electrophilic reactivities of cyclic enones and α,β-unsaturated lactones

The reactivities of cyclic enones and α,β-unsaturated lactones were characterized by following the kinetics of their reactions with colored carbon-centered reference nucleophiles in DMSO at 20 °C. The experimentally determined second-order rate constants k(2) were analyzed with the Mayr–Patz equatio...

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Vydáno v:Chem Sci
Hlavní autoři: Mayer, Robert J., Allihn, Patrick W. A., Hampel, Nathalie, Mayer, Peter, Sieber, Stephan A., Ofial, Armin R.
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2021
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179571/
https://ncbi.nlm.nih.gov/pubmed/34163736
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06628a
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