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Catalytic enantioselective allene–anhydride approach to β,γ-unsaturated enones bearing an α-all-carbon-quarternary center

A protocol of highly regio- and enantioselective copper-catalyzed hydroacylation of the non-terminal C[double bond, length as m-dash]C bond in 1,1-disubstituted terminal allenes with anhydrides has been developed. Both aromatic and aliphatic carboxylic anhydrides are applicable to the efficient cons...

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Pubblicato in:Chem Sci
Autori principali: Yuan, Yuan, Zhang, Xue, Qian, Hui, Ma, Shengming
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8161143/
https://ncbi.nlm.nih.gov/pubmed/34094192
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03227a
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