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Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes

Metal-catalyzed enantioselective construction of the loosening axial allene chirality spreading over three carbon atoms using a chiral ligand is still a significant challenge. In the literature, steric effect of the substrates is the major strategy applied for such a purpose. Herein, we present a ge...

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Publicat a:Nat Commun
Autors principals: Song, Shihua, Zhou, Jing, Fu, Chunling, Ma, Shengming
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6355870/
https://ncbi.nlm.nih.gov/pubmed/30705274
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-07908-1
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