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Selective cleavage of unactivated arene ring C–C bonds by iridium: key roles of benzylic C–H activation and metal–metal cooperativity

The cleavage of aromatic C–C bonds is central for conversion of fossil fuels into industrial chemicals and designing novel arene functionalisations through ring opening, expansion and contraction. However, the current progress is hampered by both the lack of experimental examples of selective oxidat...

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Publicat a:Chem Sci
Autors principals: Tian, Yancong, Jakoobi, Martin, Boulatov, Roman, Sergeev, Alexey G.
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179494/
https://ncbi.nlm.nih.gov/pubmed/34163630
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05900e
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