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Polyolefin catalysis of propene, 1-butene and isobutene monitored using hyperpolarized NMR

Polymerization reactions of the dissolved gases propene, 1-butene, and isobutene catalyzed by [Zr(Cp)(2)Me][B(C(6)F(5))(4)] were characterized using in situ NMR. Hyperpolarization of (13)C spins by the dissolution dynamic nuclear polarization (DNP) technique provided a signal enhancement of up to 50...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Kim, Yaewon, Samouei, Hamidreza, Hilty, Christian
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2021
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179394/
https://ncbi.nlm.nih.gov/pubmed/34164046
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05408a
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