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A case of chain propagation: α-aminoalkyl radicals as initiators for aryl radical chemistry
The generation of aryl radicals from the corresponding halides by redox chemistry is generally considered a difficult task due to their highly negative reduction potentials. Here we demonstrate that α-aminoalkyl radicals can be used as both initiators and chain-carriers for the radical coupling of a...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
The Royal Society of Chemistry
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8163300/ https://ncbi.nlm.nih.gov/pubmed/34094477 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04387g |
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