Reaction of Nitrogen‐Radicals with Organometallics Under Ni‐Catalysis: N‐Arylations and Amino‐Functionalization Cascades

Herein, we report a strategy for the generation of nitrogen‐radicals by ground‐state single electron transfer with organyl–Ni(I) species. Depending on the philicity of the N‐radical, two types of processes have been developed. In the case of nucleophilic aminyl radicals direct N‐arylation with aryl...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Angelini, Lucrezia, Davies, Jacob, Simonetti, Marco, Malet Sanz, Laia, Sheikh, Nadeem S., Leonori, Daniele
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2019
Teme:
Communications
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519068/
https://ncbi.nlm.nih.gov/pubmed/30779864
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900510
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