Reaction of Nitrogen‐Radicals with Organometallics Under Ni‐Catalysis: N‐Arylations and Amino‐Functionalization Cascades

Herein, we report a strategy for the generation of nitrogen‐radicals by ground‐state single electron transfer with organyl–Ni(I) species. Depending on the philicity of the N‐radical, two types of processes have been developed. In the case of nucleophilic aminyl radicals direct N‐arylation with aryl...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Angelini, Lucrezia, Davies, Jacob, Simonetti, Marco, Malet Sanz, Laia, Sheikh, Nadeem S., Leonori, Daniele
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519068/
https://ncbi.nlm.nih.gov/pubmed/30779864
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900510
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