A dual photoredox-nickel strategy for remote functionalization via iminyl radicals: radical ring-opening-arylation, -vinylation and -alkylation cascades

A divergent strategy for the remote arylation, vinylation and alkylation of nitriles is described. These processes proceed through the photoredox generation of a cyclic iminyl radical and its following ring-opening reaction. The distal nitrile radical is then engaged in nickel-based catalytic cycles...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Dauncey, Elizabeth M., Dighe, Shashikant U., Douglas, James J., Leonori, Daniele
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2019
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7053659/
https://ncbi.nlm.nih.gov/pubmed/32180920
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02616a
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