Photoinduced Remote Functionalisations by Iminyl Radical Promoted C−C and C−H Bond Cleavage Cascades

A photoinduced cascade strategy leading to a variety of differentially functionalised nitriles and ketones has been developed. These reactions rely on the oxidative generation of iminyl radicals from simple oximes. Radical transposition by C(sp(3))−(sp(3)) and C(sp(3))−H bond cleavage gives access t...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Dauncey, Elizabeth M., Morcillo, Sara P., Douglas, James J., Sheikh, Nadeem S., Leonori, Daniele
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2017
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5814920/
https://ncbi.nlm.nih.gov/pubmed/29114978
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201710790
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