Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

The selective functionalization of C(sp(3))−H bonds at distal positions to functional groups is a challenging task in synthetic chemistry. Reported here is a photoinduced radical cascade strategy for the divergent functionalization of amides and protected amines. The process is based on the oxidativ...

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Bibliografische gegevens
Gepubliceerd in:Angew Chem Int Ed Engl
Hoofdauteurs: Morcillo, Sara P., Dauncey, Elizabeth M., Kim, Ji Hye, Douglas, James J., Sheikh, Nadeem S., Leonori, Daniele
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: John Wiley and Sons Inc. 2018
Onderwerpen:
Communications
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6221136/
https://ncbi.nlm.nih.gov/pubmed/30074300
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201807941
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