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A case of chain propagation: α-aminoalkyl radicals as initiators for aryl radical chemistry

The generation of aryl radicals from the corresponding halides by redox chemistry is generally considered a difficult task due to their highly negative reduction potentials. Here we demonstrate that α-aminoalkyl radicals can be used as both initiators and chain-carriers for the radical coupling of a...

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Vydáno v:Chem Sci
Hlavní autoři: Constantin, Timothée, Juliá, Fabio, Sheikh, Nadeem S., Leonori, Daniele
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2020
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163300/
https://ncbi.nlm.nih.gov/pubmed/34094477
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04387g
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