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Redox deracemization of β,γ-alkynyl α-amino esters
The first non-enzymatic redox deracemization method using molecular oxygen as the terminal oxidant has been described. The one-pot deracemization of β,γ-alkynyl α-amino esters consisted of a copper-catalyzed aerobic oxidation and chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation wit...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159540/ https://ncbi.nlm.nih.gov/pubmed/34122901 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc00944j |
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