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α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration
Transition metal-free radical α-perfluoroalkylation with concomitant β-alkynylation of unactivated alkenes is presented. These cascades proceed via electron-catalysis and comprise a radical 1,4- or 1,5-alkynyl migration from tertiary propargylic alcoholates to secondary or tertiary C-radicals as the...
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| Publicado no: | Chem Sci |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5637125/ https://ncbi.nlm.nih.gov/pubmed/29147514 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02175e |
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