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Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration
Transition‐metal‐free radical α‐perfluoroalkylation with the accompanying vicinal β‐alkenylation of unactivated alkenes is presented. These radical cascades proceed by means of 1,4‐ or 1,5‐alkenyl migration by electron catalysis on readily accessed allylic alcohols. The reactions comprise a regiosel...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
John Wiley and Sons Inc.
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5838557/ https://ncbi.nlm.nih.gov/pubmed/29165859 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201710397 |
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