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Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration

A general and efficient approach for the preparation of 1,3‐bis‐(boryl)alkanes is introduced. It is shown that readily generated vinylboron ate complexes react with commercially available ICH(2)Bpin to valuable 1,3‐bis‐(boryl)alkanes. The introduced transformation, which is experimentally easy to co...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: You, Cai, Studer, Armido
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540398/
https://ncbi.nlm.nih.gov/pubmed/32579295
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007541
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