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Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration

A general and efficient approach for the preparation of 1,3‐bis‐(boryl)alkanes is introduced. It is shown that readily generated vinylboron ate complexes react with commercially available ICH(2)Bpin to valuable 1,3‐bis‐(boryl)alkanes. The introduced transformation, which is experimentally easy to co...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: You, Cai, Studer, Armido
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540398/
https://ncbi.nlm.nih.gov/pubmed/32579295
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007541
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