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Catalytic Alkene Difunctionalization via Imidate Radicals
The first catalytic strategy to harness imidate radicals has been developed. This approach enables alkene difunctionalization of allyl alcohols by photocatalytic reduction of their oxime imidates. The ensuing imidate radicals undergo consecutive intra- and inter-molecular reactions to afford either...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6519729/ https://ncbi.nlm.nih.gov/pubmed/30156404 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b07578 |
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