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Catalytic Alkene Difunctionalization via Imidate Radicals

The first catalytic strategy to harness imidate radicals has been developed. This approach enables alkene difunctionalization of allyl alcohols by photocatalytic reduction of their oxime imidates. The ensuing imidate radicals undergo consecutive intra- and inter-molecular reactions to afford either...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Nakafuku, Kohki M., Fosu, Stacy C., Nagib, David A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6519729/
https://ncbi.nlm.nih.gov/pubmed/30156404
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b07578
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