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Enantio- and diastereoselective conjugate borylation/Mannich cyclization

Strategies to capitalize on enolate intermediates generated from stereoselective conjugate borylation to α,β-unsaturated carbonyl systems are surprisingly rare despite the ubiquity of Michael acceptors, and the potential to generate valuable scaffolds bearing multiple stereocenters. Herein, we repor...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Larin, Egor M., Loup, Joachim, Polishchuk, Iuliia, Ross, Rachel J., Whyte, Andrew, Lautens, Mark
Format: Artigo
Jezik:Inglês
Izdano: The Royal Society of Chemistry 2020
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159378/
https://ncbi.nlm.nih.gov/pubmed/34094079
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc02421j
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