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Enantio- and Diastereoselective Synthesis of ( R, R)-β-Methoxytyrosine
The nonproteinogenic amino acid (2 R,3 R)-β-Methoxytyrosine, a constituent of several cyclic depsipeptide natural products, was synthesized in protected form (8) from a readily available cinnamate ester in four steps and 62% overall yield with a greater than 28:1 er and 19:1 dr. This method provides...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2688733/ https://ncbi.nlm.nih.gov/pubmed/17676746 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071350u |
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