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Enantio- and Diastereoselective Synthesis of N-Acetyl Dihydrotetrafibricin Methyl Ester

A highly diastereoselective synthesis of N-acetyl dihydrotetrafibricin methyl ester (34) is described. The synthesis features three enantioselective double allylboration reactions, an intramolecular hydrosilylation/Tamao-Fleming oxidation sequence to establish seven of the hydroxy-bearing stereocent...

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Bibliografiske detaljer
Main Authors: Nuhant, Philippe, Roush, William R.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3679187/
https://ncbi.nlm.nih.gov/pubmed/23530855
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401918r
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