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Enantio- and Diastereoselective Synthesis of N-Acetyl Dihydrotetrafibricin Methyl Ester
A highly diastereoselective synthesis of N-acetyl dihydrotetrafibricin methyl ester (34) is described. The synthesis features three enantioselective double allylboration reactions, an intramolecular hydrosilylation/Tamao-Fleming oxidation sequence to establish seven of the hydroxy-bearing stereocent...
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| Autores principales: | , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2013
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3679187/ https://ncbi.nlm.nih.gov/pubmed/23530855 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401918r |
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