(Diisopinocampheyl)borane-Mediated Reductive Aldol Reactions: Highly Enantio and Diastereoselective Synthesis of Syn-Aldols from N-Acryloylmorpholine()

[Image: see text] An efficient and highly enantio- and diastereoselective synthesis of syn propionamide aldols is described. Formation of the Z-enolborinate via the hydroboration of 4-acryloylmorpholine with (diisopinocampheyl)borane followed by aldol reactions with representative achiral and chiral...

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Detalhes bibliográficos
Main Authors: Nuhant, Philippe, Allais, Christophe, Roush, William R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3813003/
https://ncbi.nlm.nih.gov/pubmed/23818095
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201302535
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