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A designed second-sphere hydrogen-bond interaction that critically influences the O–O bond activation for heterolytic cleavage in ferric iron–porphyrin complexes
Heme hydroperoxidases catalyze the oxidation of substrates by H(2)O(2). The catalytic cycle involves the formation of a highly oxidizing species known as Compound I, resulting from the two-electron oxidation of the ferric heme in the active site of the resting enzyme. This high-valent intermediate i...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
The Royal Society of Chemistry
2020
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8157560/ https://ncbi.nlm.nih.gov/pubmed/34084327 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04388h |
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