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Heterolytic H(2) Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane
Reversible, heterolytic addition of H(2) across an iron-boron bond in a ferraboratrane with formal hydride transfer to the boron gives iron-borohydrido-hydride complexes. These compounds catalyze the hydrogenation of alkenes and alkynes to the respective alkanes. Notably, the boron is capable of act...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2013
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3757927/ https://ncbi.nlm.nih.gov/pubmed/24000270 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400281v |
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