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N(2) Functionalization at Iron Metallaboratranes
The reactivity of the anionic dinitrogen complex [(TPB)Fe(N(2))](−) (2, TPB = tris-[2-(diisopropylphosphino)phenyl]borane) towards silicon electrophiles has been examined. Compound 2 reacts with trimethylsilyl chloride (TMSCl) to yield the silyldiazenido complex (TPB)Fe(NNSiMe(3)) (3), which is redu...
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| Hlavní autoři: | , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2011
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3212643/ https://ncbi.nlm.nih.gov/pubmed/22008018 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208675p |
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