Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications

A synthetic strategy for the 2-phospha-1,3-butadiene derivatives [{(IPr)C(Ph)}P(cAAC(Me))] (3a) and [{(IPr)C(Ph)}P(cAAC(Cy))] (3b) (IPr = C{(NDipp)CH}(2), Dipp = 2,6-iPr(2)C(6)H(3); cAAC(Me) = C{(NDipp)CMe(2)CH(2)CMe(2)}; cAAC(Cy) = C{(NDipp)CMe(2)CH(2)C(Cy)}, Cy = cyclohexyl) containing a C[double...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Sharma, Mahendra K., Blomeyer, Sebastian, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, Hinz, Alexander, van Gastel, Maurice, Ghadwal, Rajendra S.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: The Royal Society of Chemistry 2020
Gaiak:
Chemistry
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC8148328/
https://ncbi.nlm.nih.gov/pubmed/34123292
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05598c
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