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Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications
A synthetic strategy for the 2-phospha-1,3-butadiene derivatives [{(IPr)C(Ph)}P(cAAC(Me))] (3a) and [{(IPr)C(Ph)}P(cAAC(Cy))] (3b) (IPr = C{(NDipp)CH}(2), Dipp = 2,6-iPr(2)C(6)H(3); cAAC(Me) = C{(NDipp)CMe(2)CH(2)CMe(2)}; cAAC(Cy) = C{(NDipp)CMe(2)CH(2)C(Cy)}, Cy = cyclohexyl) containing a C[double...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8148328/ https://ncbi.nlm.nih.gov/pubmed/34123292 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05598c |
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