An Open‐Shell Singlet Sn(I) Diradical and H(2) Splitting

The first Sn(I) diradical [(ADC(Ph))Sn](2) (4) based on an anionic dicarbene (ADC(Ph)={CN(Dipp)}(2)CPh; Dipp=2,6‐iPr(2)C(6)H(3)) scaffold has been isolated as a green crystalline solid by KC(8) reduction of the corresponding bis‐chlorostannylene [(ADC(Ph))SnCl](2) (3). The six‐membered C(4)Sn(2)‐rin...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Sharma, Mahendra K., Rottschäfer, Dennis, Glodde, Timo, Neumann, Beate, Stammler, Hans‐Georg, Ghadwal, Rajendra S.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2021
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986611/
https://ncbi.nlm.nih.gov/pubmed/33460280
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202017078
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