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An Open‐Shell Singlet Sn(I) Diradical and H(2) Splitting
The first Sn(I) diradical [(ADC(Ph))Sn](2) (4) based on an anionic dicarbene (ADC(Ph)={CN(Dipp)}(2)CPh; Dipp=2,6‐iPr(2)C(6)H(3)) scaffold has been isolated as a green crystalline solid by KC(8) reduction of the corresponding bis‐chlorostannylene [(ADC(Ph))SnCl](2) (3). The six‐membered C(4)Sn(2)‐rin...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7986611/ https://ncbi.nlm.nih.gov/pubmed/33460280 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202017078 |
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