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Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides
A series of unique C(2)P(3)-ring compounds [(ADC(Ar))P(3)] (ADC(Ar) = ArC{(DippN)C}(2); Dipp = 2,6-iPr(2)C(6)H(3); Ar = Ph 4a, 3-MeC(6)H(4)4b, 4-MeC(6)H(4)4c, and 4-Me(2)NC(6)H(4)4d) are readily accessible in an almost quantitative yield by the direct functionalization of white phosphorus (P(4)) wit...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7069227/ https://ncbi.nlm.nih.gov/pubmed/32206256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc04441h |
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